Approximately 20-30 minutes before baking, remove the pork chops from the refrigerator and allow them to rest at room temperature.
Preheat the oven to 400°F (200°C) and spray a 9×13-inch baking dish or rimmed baking sheet lined with foil with non-stick cooking spray (or coat lightly with olive oil).
In a small bowl, stir together the brown sugar, paprika, garlic powder, onion powder, salt, and pepper.
Pat the pork chops dry with paper towels, then sprinkle the dry rub evenly over both sides. Use your fingers to rub it in gently.
Transfer the seasoned pork chops to the prepared baking dish or baking sheet and drizzle the tops of the chops with the remaining olive oil.
Bake for 15-25 minutes. Cooking time will vary depending on whether you’re cooking bone-in or boneless chops and their thickness (I start checking around 10-12 minutes if my pork chops are on the thinner side). In the last 2-3 minutes, broil on high until crisp around the edges and golden on top.
Remove from the oven as soon as the internal temperature registers 145ºF as measured by a digital meat thermometer. Rest for at least 3-5 minutes before serving with mashed potatoes and any other favorite side dishes.